Kniha Supported Metal Complexes F.R. Hartley

Supported Metal Complexes

A New Generation of Catalysts

Autor: F.R. Hartley
Jazyk: Angličtina
Väzba: Brožovaná
Vydavateľ: Springer
Dostupnosť: Skladom u dodávateľa v malom množstve
Odosielame za 13-18 dní
54.21
It is now IS years since the first patents in polymer supported metal complex catalysts were taken o...

Informácie o knihe

Autor
Jazyk
Angličtina
Väzba
Kniha - Brožovaná
Vydalo
2011
Stránok
340
EAN
9789401088176
ISBN
9401088179
Enbook ID
02185641
Vydavateľ
Hmotnosť
522
Rozmery
155 x 235 x 19

Kompletný popis

It is now IS years since the first patents in polymer supported metal complex catalysts were taken out. In the early days ion-exchange resins were used to support ionic metal complexes. Soon covalent links were developed, and after an initially slow start there was a period of explosive growth in the mid to late 1970s during which virtually every homogeneous metal complex catalyst ever reported was also studied bound to a support. Both polymers and inorganic oxides were studied as supports, although the great preponderance of workers studied polymeric supports, and of these polystyrene was by far the commonest used. This period served to show that by very careful design polymer-supported metal complex catalysts could have specific advantages over homogeneous metal complex catalysts. However the subject was a complicated one. Merely immobilising a successful metal complex catalyst to a functionalised support rarely yielded other than an inferior version of the catalyst. Amongst the many discouraging results of the 1970s, there were more than enough results that were sufficiently encouraging to demonstrate that, by careful design, supported metal complex catalysts could be prepared in which both the metal complex and the support combined together to produce an active catalyst which, due to the combination of support and complex, had advantages of activity, selectivity and specificity not found in homogeneous catalysts. Thus a new generation of catalysts was being developed.

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