3D Velocity Map Imaging: Instrument Design and Application to Quantum State Selective Reaction Dynamics

Name: 3D Velocity Map Imaging: Instrument Design and Application to Quantum State Selective Reaction Dynamics
Brand: Cuvillier Verlag
SKU: 9783869553573
Price: 38.16 EUR
Availability: InStock

Autor: Sebastian Kauczok

Jazyk:

Väzba: Brožovaná

Vydavateľ: Cuvillier Verlag

Dostupnosť: Skladom u dodávateľa

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38.16 €

The book has been written as a dissertation on the University of Braunschweig, Germany under supervi...

Informácie o knihe

Autor

Sebastian Kauczok

Jazyk

Angličtina

Väzba

Kniha - Brožovaná

Vydalo

2010

Stránok

280

EAN

9783869553573

ISBN

386955357X

Enbook ID

12738483

Vydavateľ

Cuvillier Verlag

Hmotnosť

366

Rozmery

148 x 210 x 15

Kompletný popis

The book has been written as a dissertation on the University of Braunschweig, Germany under supervision of Prof. Dr. Karl-Heinz Gericke. It deals with thedevelopment, description and application of a three dimensional velocity map imaging technique for products of elementary chemical reactions such as photodissociations and reactive collisions. By means of REMPI spectroscopy the quantum state of the products is also resolved. In contrast to earlier reports of 3D velocity mapping techniques that were based on 2D velocity map imaging and the specific time of flight spectrometer used for this, the technique presented is an enhancement of 3D ion imaging and its one field spectrometer. As a result, the time broadening due to the kinetic energy release and therefore the resolution in the third dimension is much larger than for the techniques reported earlier having a rather poor time resolution despite comparable detector features.The processes studied comprise: i)The reactive collision dynamics of O(1D) with D2 as a proof for a novel technique to study photoinitiated bimolecular reactions being a hybrid of the PHOTOLOC technique and the parallel beams technique used by the groups of Kitsopoulos, Orr-Ewing and Suits.ii) The photodissociation dynamics of the B1S+ double minimum state of HCl accessed by two-photon absorption. iii) The dynamics of the constrained geometry reaction of O(1D) and N2O inside the(N2O)2 dimer.

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3D Velocity Map Imaging: Instrument Design and Application to Quantum State Selective Reaction Dynamics

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Kompletný popis

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